Your Results for:
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 ADVACor® ABR Absorption Refrigerant
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| Market: Air Treatment |
| SubMarket: Absorption Chilling |
| CAS #: 7732-18-5 |
| Description: Refrigerant for Absorption Chillers
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| ADVACor® Lithium Bromide Solution
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| Market: Air Treatment |
| SubMarket: Absorption Chilling |
| CAS #: 7732-18-5 |
| Description: Uninhibited Lithium Bromide Solution - Absorption component of refrigerant system in absorption chillers.
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 ADVAGuard® 290 Corrosion Inhibitor
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| Market: Air Treatment |
| SubMarket: Corrosion Inhibitors |
| CAS #: 1310-66-3 |
| Description: Lithium Hydroxide Monohydrate - pH correction, in lithium bromide and lithium chloride solution.
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 ADVAGuard® 390 Corrosion Inhibitor
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| Market: Air Treatment |
| SubMarket: Corrosion Inhibitors |
| CAS #: 7790-69-4 |
| Description: Lithium nitrate solution (30 wt%) corrosion inhibitor, in lithium bromide solutions.
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 ADVAGuard® 391 Corrosion Inhibitor
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| Market: Air Treatment |
| SubMarket: Corrosion Inhibitors |
| CAS #: 7790-69-4 |
| Description: Lithium Nitrate Anhydrous for corrosion inhibitor, in lithium bromide solutions.
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 ADVAGuard® 590 Corrosion Inhibitor
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| Market: Air Treatment |
| SubMarket: Corrosion Inhibitors |
| CAS #: 13568-40-6 |
| Description: Lithium molybdate solution (30 wt%) corrosion inhibitor, in lithium bromide solution and lithium chloride.
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 ADVAGuard® 591 Corrosion Inhibitor
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| Market: Air Treatment |
| SubMarket: Corrosion Inhibitors |
| CAS #: 13568-40-6 |
| Description: Lithium molybdate crystals corrosion inhibitor, in lithium bromide solution and lithium chloride.
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| Cyclopentyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
Description: This base is used as an alkylating or metalating reagent.
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| Dibutylmagnesium 14% in Hexane
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| Market: Fine Chemicals |
| SubMarket: Organomagnesiums |
| CAS #: 39881-32-8 |
Description: DBM is a hydrocarbon soluble, non-pyrophoric dialkylmagnesium compound. In order to increase hydrocarbon solubility, there is a 10 mole% n-octyl group also present. DBM is used to metalate amines, alcohols, and other acidic substrates to afford the corresponding magnesium compounds. DBM is also an excellent indirect source of anhydrous MgCl2 or MgBr2, when reacted with the appropriate anhydrous acid or halogenating reagent. DBM is used as a promoter for Ziegler-Natta polyolefin catalyst systems. For leading references, consult 1) Polymer 1995, 36, 2995; 2) Polymer International, John Wiley & Sons:2002; Vol. 51 (8), pp 729-737.
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| Dibutylmagnesium 14% in Hexane
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| Market: Polymers |
| SubMarket: Catalyst |
| CAS #: 39881-32-8 |
Description: DBM is a hydrocarbon soluble, non-pyrophoric dialkylmagnesium compound. In order to increase hydrocarbon solubility, there is a 10 mole% n-octyl group also present. DBM is used to metalate amines, alcohols, and other acidic substrates to afford the corresponding magnesium compounds. DBM is also an excellent indirect source of anhydrous MgCl2 or MgBr2, when reacted with the appropriate anhydrous acid or halogenating reagent. DBM is used as a promoter for Ziegler-Natta polyolefin catalyst systems. For leading references, consult 1) Polymer 1995, 36, 2995; 2) Polymer International, John Wiley & Sons: 2002; Vol. 51 (8), pp 729-737.
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| Di-t-butylneopentylphosphine
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| Market: Fine Chemicals |
| SubMarket: Organophosphines |
Description: DTBNpP is a DEVELOPMENTAL product which is used as a ligand in metal catalyzed coupling reactions (Suzuki, Heck, Sonagashira, formylations, aminations, and hydrogenations). This reagent is also used in catalytic polymerization reactions. For general reviews of phosphine applications see: 1) Palladium Reagents and Catalysts, John Wiley & Sons: Chichester, 1995 p. 345-356. 2) Advanced Synthesis & Catalysts, Wiley-VCH Verlag GmbH 2001 p. 118-136.
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| Di-t-butylsilyl ditriflate
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| Market: Fine Chemicals |
| SubMarket: Organosilanes |
Description: This ditriflate silane is typically used as a protecting groups for diols such as nucleosides in organic synthesis. References: (1) Corey, E.J.; Hopkins, P.B. Tetrahedron Lett. 23, 47, 1982, 4871. (2) Furusawa, K.; Ueno, K.; Karsura, T. Chem Lett., 1990, 97.
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| Di-tert-butylsilane (DTBS)
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| Market: Fine Chemicals |
| SubMarket: Organosilanes |
| CAS #: 30736-07-3 |
Description: Di–tert–butylsilane is a DEVELOPMENTAL product and can be employed to install the highly hindered di-t-butylsilylene group for the protection of 1,2 and 1,3 diols. The formation of this protecting group can be catalyzed by Pd/C (K. Yamamoto and M. Takemae, Bull. Chem. Soc. Jpn., 1989, 62, 2111) or fluoride ion (Y. Tanabe et al, Tetradron Lett., 1994, 35, 8409). Di–tert–butylsilane can also be employed as a sterically hindered reducing agent. Upon thermolysis, Di–tert–butylsilane serves as a source of silicon for the CVD of silicon carbide (J. M. Grow, Proc. Electrochem. Soc., 1996, 96, 60).
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| Ethyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
Description: This base is used as an alkylating or metalating reagent.
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| Isobutyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 920-36-5 |
Description: This base is used as an alkylating or metalating reagent.
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| Isobutyllithium 20% in Hexanes (IBL)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 920-36-5 |
Description: Isobutyllithium in hexanes is a DEVELOPMENTAL product. This organolithium species is an excellent nucleophile for the addition of an isobutyl moiety into an organic or organometallic substrate. A higher yield of the addition product was obtained with IBL versus the corresponding Grignard reagent, see Z. Han, D. Krishnamurthy, D. Pflum, P. Grover, S. A. Wald and C. H. Senanayake, Org. Lett., 202, 4, 4025.
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| Isopropyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
Description: This base is used as an alkylating or metalating reagent.
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| Isopropylmagnesium chloride
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| Market: Fine Chemicals |
| SubMarket: Organomagnesiums |
| CAS #: 1068-55-9 |
Description: Isopropylmagnesium chloride, namely a Grignard reagent, is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. For reviews see: 1) J.Am.Chem.Soc. 1967, 89, 1964; 2) Synthesis 1977, 18; and 3) Pure Appl. Chem. 1980.
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 Lectro® Lyte 500, Lithium Bromide
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| Market: Energy |
| SubMarket: Salts |
| CAS #: 7550-35-8 |
| Description: An electrochemical grade of lithium bromide used as a component of the electrolyte in lithium batteries.
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 Lectro® Lyte 600, Lithium Chloride
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| Market: Energy |
| SubMarket: Salts |
| CAS #: 7447-41-8 |
| Description: An electrochemical grade of lithium chloride used as a component of the electrolyte in lithium batteries.
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 Lectro® Lyte 700, Lithium Fluoride
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| Market: Energy |
| SubMarket: Salts |
| CAS #: 7789-24-4 |
| Description: An electrochemical grade of lithium fluoride used as a component of the electrolyte in lithium batteries.
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 Lectro® Lyte 800, Lithium Nitrate
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| Market: Energy |
| SubMarket: Salts |
| CAS #: 7790-69-4 |
| Description: An electrochemical grade of lithium nitrate used as a component of the electrolyte in batteries.
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 Lectro® Lyte 900, Lithium Hydroxide
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| Market: Energy |
| SubMarket: Salts |
| CAS #: 1310-66-3 |
| Description: An electrochemical grade of lithium hydroxide monohydrate used as an additive to the electrolyte solution for batteries.
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 Lectro® Max 100, Lithium Foil
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium foil, custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 120, Lithium Aluminum Alloy Foil
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium aluminum alloy foil (Al <4wt%), custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries offering enhanced properties not available with pure Lithium while maintaining similar electrochemical equivalence. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 130, Lithium Magnesium Alloy Foil
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium magnesium alloy foil, custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries offering enhanced properties not available with pure Lithium while maintaining similar electrochemical equivalence. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 210, Li Foil with Copper Current Collector
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium foil supplied with a copper current collector, custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries. Standard product offering utilizes a 0.003" x 0.125" copper strip that can be laminated in a single, double or triple strip configuration. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 220, Li Foil with Nickel Current Collector
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium foil supplied with a nickel current collector, custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries. Standard product offering utilizes a 0.006" diameter wire that can be laminated in a single, double or triple wire configuration. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 300, Lithium Engineered Precuts
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade engineered precuts, custom made to your unique dimensional requirements within FMC's extensive capability, are used as the anode in lithium batteries. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 400, Lithium Ingot
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade lithium ingot, custom made to your diameter and length requirements within FMC's extensive capability, is used as the anode in lithium batteries. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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 Lectro® Max 410, Lithium Aluminum Alloy Ingot
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| Market: Energy |
| SubMarket: Anode Materials |
| CAS #: 7439-93-2 |
| Description: Electrochemical grade aluminum lithium alloy ingot, custom made to your dimensional requirements within FMC's extensive capability, is used as the anode in lithium batteries offering enhanced properties not available with pure Lithium while maintaining similar electrochemical equivalence. Lithium, being both the lightest and the most electronegative, provides the highest electrochemical equivalence of all metals.
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| Lectro® Max Powder 100, SLMP®
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| Market: Energy |
| SubMarket: New Technology/Products |
| CAS #: 7439-93-2 |
| Description: Lectro Max Powder, a proprietary stabilized lithium metal powder (SLMP), is utilized to improve battery performance, reduce costs, and enhance safety by enabling the use of new anode and cathode materials. SLMP can be added to the cell to produce a fully lithiated anode, which can be used with non-lithiated cathodes. It can also be added to existing or new anodes to compensate for the irreversibility.
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 LifeTech® Superfines
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| Market: Construction |
| SubMarket: Accelerators |
| CAS #: 554-13-2 |
| Description: LifeTech fines are a chemical admixture that can be used to adjust and accelerate the setting time of cementitious systems such as high-alumina cements (HAC) and alumina-portland cement blends. Common applications for HAC and HAC/PC blends include: refractory cements, shotcrete / gunite, self-leveling floor systems, quickset adhesives, quickset mortars and rapid-repair materials. LifeTech Superfines are the medium fine of the LifeTech grades of lithium carbonate available from FMC. Because of its fine particle size and narrow particle size distribution, this product has been chosen as the grade of choice where reactivity and performance are based on the surface area of the lithium carbonate particles providing controllable, uniform and predictable rates of reaction. Since it is the medium of the grades, it is not as reactive as the ultrafines, but more reactive than the fines.
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 LifeTech® Ultrafines
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| Market: Construction |
| SubMarket: Accelerators |
| CAS #: 554-13-2 |
| Description: LifeTech fines are a chemical admixture that can be used to adjust and accelerate the setting time of cementitious systems such as high-alumina cements (HAC) and alumina-portland cement blends. Common applications for HAC and HAC/PC blends include: refractory cements, shotcrete / gunite, self-leveling floor systems, quickset adhesives, quickset mortars and rapid-repair materials. Life Tech Ultrafines are the finest of the LifeTech grades of lithium carbonate available from FMC. Because of its fine particle size and narrow particle size distribution, this product has been chosen as the grade of choice where reactivity and performance are based on the surface area of the lithium carbonate particles providing controllable, uniform and predictable rates of reaction. Since it is the finest of the grades, it is also the most reactive in these situations.
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 LifeTime® N Admixture
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| Market: Construction |
| SubMarket: Admixtures |
| CAS #: 7790-69-4 |
| Description: Lithium nitrate solution for the prevention of Alkali-Silica Reactivity (ASR) in concrete.
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 LifeTime® SL Admixture
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| Market: Construction |
| SubMarket: Admixtures |
| CAS #: 1310-66-3 |
| Description: Lithium hydroxide crystal used to prevent Alkali-Silica Reactivity (ASR) in concrete. Also used in corrosion protection of rebar in concrete in passive cathodic inhibiting systems.
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 LiMIT® 101
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| Market: Air Treatment |
| SubMarket: Dehumidification |
| CAS #: 7447-41-8 |
| Description: Uninhibited Lithium Chloride dehumidification system solution
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 LiMIT® 201
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| Market: Air Treatment |
| SubMarket: Dehumidification |
| CAS #: 7447-41-8 |
| Description: Lithium Chloride Solution - Molybdate inhibited Dehumidification system solution.
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 LiMIT® 301
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| Market: Air Treatment |
| SubMarket: Dehumidification |
| CAS #: 7447-41-8 |
| Description: Corrosion inhibiting Dehumidifying system solution
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| Lithium 2-Hydroxyethoxide Slurry
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 23248-23-9 |
| Description: Used in the production of polymer films.
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| Lithium Acetate Dihydrate
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| Market: Specialty Applications |
| SubMarket: Dyestuffs |
| CAS #: 6108-17-4 |
| Description: Commonly used in polymers, textiles and specialty applications to improve lubricity, smoothness, dye-ability, and to decrease luster and breaks.
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| Lithium Acetate Solution
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| Market: Specialty Applications |
| SubMarket: Dyestuffs |
| CAS #: 546-89-4 |
| Description: Commonly used in polymers, textiles and specialty applications to improve lubricity, smoothness, dye-ability, and to decrease luster and breaks.
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| Lithium Amide
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| Market: Fine Chemicals |
| SubMarket: Lithium Amides |
| CAS #: 7782-89-0 |
Description: Lithium amide is a strong base used primarily in organic synthesis. Typical reactions reported for lithium amide include aldol condensations, alkylations of heterocyclic amines, and formation of cyclopropenes. It is also proven an effective catalyst in transesterification reactions. For leading references, consult 1) J. Am. Chem. Soc. 1894, 65, 517; 2) Handbook in Preparative Inorganic Chemistry, Academic Press, New York, 2nd Ed, 1963, p 463.
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| Lithium Amide
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| Market: Polymers |
| SubMarket: Polymer Additives |
| CAS #: 7782-89-0 |
Description: Lithium amide is a strong base used primarily in organic synthesis. Typical reactions reported for lithium amide include aldol condensations, alkylations of heterocyclic amines, and formation of cyclopropenes. It is also proven an effective catalyst in transesterification reactions. For leading references, consult 1) J. Am. Chem. Soc. 1894, 65, 517; 2) Handbook in Preparative Inorganic Chemistry, Academic Press, New York, 2nd Ed, 1963, p 463.
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| Lithium Bromide Anhydrous
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7550-35-8 |
| Description: Reconstitution of brines, swelling agent for proteins, a humectant and fungicide in medicinals, electrolyte component in lithium batteries. In organic reactions, as a catalyst and dehydrohalogenating agent and in O-demethylation.
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| Lithium Bromide Solutions (Inhibited)
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| Market: Air Treatment |
| SubMarket: Absorption Chilling |
| CAS #: 7550-35-8 |
| Description: Corrosion inhibited Lithium Bromide Solution - Absorption component of refrigerant system in absorption chillers.
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| Lithium Bromide Solutions (Uninhibited)
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| Market: Air Treatment |
| SubMarket: Absorption Chilling |
| CAS #: 7550-35-8 |
| Description: Uninhibited Lithium Bromide Solution - Absorption component of refrigerant system in absorption chillers.
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| Lithium Carbonate, ACS Grade
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 554-13-2 |
| Description: Additive in specialty glasses and low-expansion ceramics, analytical agent.
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| Lithium Carbonate, Battery Grade
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| Market: Energy |
| SubMarket: Energy Precursors |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.5 wt% purity and a relatively fine particle size. Battery grade product is a superior purity grade product for use as a precursor in making critical battery materials.
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| Lithium Carbonate, Industrial Grade
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| Market: Glass and Ceramics |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.0 wt% purity and a relatively fine particle size. Industrial Grade product is useful in the manufacture of glass, frits, other ceramics and a variety of specialized applications.
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| Lithium Carbonate, Micronized Battery Grade
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| Market: Energy |
| SubMarket: Energy Precursors |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.5 wt% purity and a 5 µm D50 particle size. Micronized Battery grade product is a superior purity grade product for use as a precursor in making critical battery materials.
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| Lithium Carbonate, Micronized Technical Grade
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| Market: Energy |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.3 wt% purity and a 5 µm D50 particle size. Micronized Technical Grade product is a higher purity grade product for use as a precursor in making critical battery materials, is useful in the manufacture of glass, frits, other ceramics and a variety of specialized applications.
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| Lithium Carbonate, Micronized Technical Grade
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| Market: Glass and Ceramics |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.3 wt% purity and a 5 µm D50 particle size. Micronized Technical Grade product is a higher purity grade product for use as a precursor in making critical battery materials, is useful in the manufacture of glass, frits, other ceramics and a variety of specialized applications.
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| Lithium Carbonate, Pharmaceutical Grade
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| Market: Fine Chemicals |
| SubMarket: Active Ingredients |
| CAS #: 554-13-2 |
Description: Pharmaceutical grade approved by FDA for treatment of bipolar disorder and manic depressive psychosis. A comprehensive text book by Dr. F. N. Johnson, titled Lithium Research and Therapy [Academic Press, NY, 1975], gives details regarding medical applications for lithium and includes recommended procedures for the treatment of a patient suffering from lithium poisoning.
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| Lithium Carbonate, Technical Grade
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| Market: Glass and Ceramics |
| SubMarket: Energy Precursors |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.3 wt% purity and a relatively fine particle size. Technical Grade product is a higher purity grade for use as a precursor in making critical battery materials, is useful in the manufacture of glass, frits, other ceramics and a variety of specialized applications.
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| Lithium Carbonate, Technical Grade
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| Market: Energy |
| SubMarket: Energy Precursors |
| CAS #: 554-13-2 |
| Description: A free-flowing, odorless white powder with guaranteed 99.3 wt% purity and a relatively fine particle size. Technical Grade product is a higher purity grade for use as a precursor in making critical battery materials, is useful in the manufacture of glass, frits, other ceramics and a variety of specialized applications.
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| Lithium Chloride ACS Grade
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7447-41-8 |
| Description: ACS grade used for Electrolyte for dry cells used at low temperatures, catalyst in certain oxidation reactions, solubilizer for polyamides and cellulose when used with amide solvents, chlorinating agent for steroid substrates.
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| Lithium Chloride Anhydrous Purified
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7447-41-8 |
| Description: Electrolyte for dry cells used at low temperatures, catalyst in certain oxidation reactions, solubilizer for polyamides and cellulose when used with amide solvents, chlorinating agent for steroid substrates.
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| Lithium Chloride Anhydrous Technical Grade
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7447-41-8 |
| Description: Molten salt chemistry and metallurgy, brazing fluxes, catalyst for organic oxidation reactions, electrolyte in dry cells used in low temperatures, and stabilizer in textile fiber spinning solutions. Solubilizer for polyamides and cellulose when used with amide solvents, chlorinating agent for steroid agents. Desiccant for drying applications, tracer in wastewater.
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| Lithium Chloride Bleach
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| Market: Specialty Applications |
| SubMarket: Bleaching |
| CAS #: 13840-33-0 |
| Description: A free-flowing, granular, 30-35% available chlorine form of Lithium Hypochlorite intended solely for industrial uses such as for bleaching. This product is not intended for any application claiming biocidal activity and is not registered with the EPA for any such use.
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| Lithium Chloride Industrial Grade
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7447-41-8 |
| Description: Molten salt chemistry and metallurgy, brazing fluxes, catalyst for organic oxidation reactions, electrolyte in dry cells used in low temperatures, and stabilizer in textile fiber spinning solutions. Solubilizer for polyamides and cellulose when used with amide solvents, chlorinating agent for steroid agents. Desiccant for drying applications, tracer in wastewater.
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| Lithium Chloride Solution
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7447-41-8 |
| Description: Deicing solutions, low-freezing solutions for fire extinguishers, catalyst, and dehumidifying systems, photosensitive developer compositions, tracer in wastewater.
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| Lithium Citrate Tetrahydrate
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 6080-58-6 |
| Description: Curing agent in concrete and numerous other applications.
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| Lithium Diisopropylamide (LDA 9500)
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| Market: Fine Chemicals |
| SubMarket: Lithium Amides |
| CAS #: 4111-54-0 |
Description: LDA is a non-pyrophoric hindered non-nucleophilic strong base widely used for the generation of carbanions1, including the initiation of anionic polymerization2. (1) Wakefield Organolithium Methods; Academic Press: New York, 1988, 32-44. (2) J.Polym.Sci. Part A: Polym. Chem. 1994, 32, 2425. This product circumvents the generation and evolution of butane associated with the preparation of LDA by the reaction of n-butyllithium and diisopropylamine.
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| Lithium Diisopropylamide (LDA 9505)
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| Market: Fine Chemicals |
| SubMarket: Lithium Amides |
| CAS #: 4111-54-0 |
Description: LDA is a non-pyrophoric hindered non-nucleophilic strong base widely used for the generation of carbanions1, including the initiation of anionic polymerization2. (1) Wakefield Organolithium Methods; Academic Press: New York, 1988, 32-44. (2) J.Polym.Sci. Part A: Polym. Chem. 1994, 32, 2425. THIS PRODUCT CIRCUMVENTS THE GENERATION AND EVOLUTION OF BUTANE ASSOCIATED WITH THE PREPARATION OF LDA BY THE REACTION OF N-BUTYLLITHIUM AND DIISOPROPYLAMINE. LDA 9505 IS SIGNIFICANTLY MORE STABLE THAN LDA 9500.
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| Lithium Ethoxide
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
Description: This alkoxide base is used for condensation and alkylation reactions.
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| Lithium Fluoride Technical Grade
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7789-24-4 |
| Description: Powerful flux in enamels, glasses and glazes, ingredient in brazing and welding fluxes, molten salt chemistry and metallurgy, and heat sink material.
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| Lithium Hexamethyldisilazide (LHS) 24% in THF
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| Market: Fine Chemicals |
| SubMarket: Lithium Amides |
| CAS #: 4039-32-1 |
Description: LHS is a non-pyrophoric strong base, widely employed in organic synthesis as a metalation agent. The principle advantages of this reagent are the improved selectivity obtained in deprotonation reactions and the enhanced thermal stability. It is employed as a base in generating enolates for the preparation of lactone precursors. (1) J.Org. Chem. 1993, 58, 7304. (2) Synlett 1993, 507. (3) Tetrahedron 1994, 50, 9061. LHS is offered in THF solution and therefore, is very easy to transfer from shipping container to storage or a reactor. LHS is a more stable base than LDA or lithium diisopropylamide, which is also available from FMC.
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| Lithium Hydroxide Anhydrous
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 1310-65-2 |
| Description: Intermediates generator in organic synthesis catalyst in alkyd resin manufacture and esterification reactions, stabilizer in some photographic developers, and heat sink material. Absorption of carbon dioxide from sealed environments, as in submarines, spacecraft, and self-contained breathing apparatus.
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| Lithium Hydroxide Monohydrate Fines
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| Market: Greases and Lubricants |
| SubMarket: Products |
| CAS #: 1310-66-3 |
| Description: A free-flowing, granular solid with a much smaller average particle size than the Technical or other grades offered by FMC Lithium. The product is well suited for use in applications where greater reactivity and larger surface area is a benefit.
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| Lithium Hydroxide Monohydrate Purified
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| Market: Specialty Applications |
| CAS #: 1310-66-3 |
Description: A free-flowing, granular solid with greatly reduced levels of CaO, NaOH and Mg. Purified grade is useful for the manufacture of fine chemicals and specialty greases. A product with reduced levels of SiO2 is also available.
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| Lithium Hydroxide Monohydrate, Battery Grade
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| Market: Energy |
| CAS #: 1310-66-3 |
| Description: A free-flowing, granular solid with greatly reduced levels of CaO, NaOH and Mg. Battery grade is suitable for use in production of cathode materials for lithium ion batteries.
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| Lithium Hydroxide Monohydrate, Technical Grade
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| Market: Energy |
| CAS #: 1310-66-3 |
| Description: A free-flowing, granular solid well suited for use in the manufacture of lithium greases, dyestuffs, specialty resins and many other chemical specialities. It has a narrow particle size distribution and a low fines content.
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| Lithium Hydroxide Monohydrate, Technical Grade
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| Market: Greases and Lubricants |
| SubMarket: Products |
| CAS #: 1310-66-3 |
| Description: A free-flowing, granular solid well suited for use in the manufacture of lithium greases, dyestuffs, specialty resins and other chemical specialties. It has a narrow particle size distribution and a low fines content.
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| Lithium Hydroxide, Electrolyte Grade
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| Market: Energy |
| SubMarket: Energy Precursors |
| CAS #: 1310-66-3 |
| Description: This very high purity grade product is a critical component in making high performance battery materials and very high purity specialty products.
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| Lithium Hypochlorite
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| Market: Specialty Applications |
| SubMarket: Industrial Sanitation |
| CAS #: 13840-33-0 |
| Description: A free-flowing, granular, 35% available chlorine solid intended solely for industrial sanitation and water treatment. It is well suited for formulation in products claiming biocidal activity or as a stand-alone product. This product is registered with the EPA for its intended use.
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| Lithium Hypochlorite
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| Market: Pool Water Treatment |
| SubMarket: Products |
| CAS #: 13840-33-0 |
| Description: A free-flowing, granular, 35% available chlorine solid intended solely for swimming pool and spa sanitation and shock. Lithium Hypochlorite offers superior cold water solubility and hardness and pH control and is particularly well suited for vinyl liner pools and spas. This product is registered with the EPA for its intended use.
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| Lithium Metal, Alloy Grade
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| Market: Specialty Applications |
| SubMarket: Lithium Metal |
| CAS #: 7439-93-2 |
| Description: Used in the production of lightweight aluminum lithium alloys, magnesium lithium alloys, and other similar lightweight metal applications, lithium metal enhances the finished properties.
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| Lithium Metal, Alloy Grade High Purity
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| Market: Specialty Applications |
| SubMarket: Lithium Metal |
| CAS #: 7439-93-2 |
| Description: High purity alloy grade lithium metal with a lower impurity profile than our standard alloy grade metal is offered to meet the demanding requirements of the production of lightweight aluminum lithium alloys, magnesium lithium alloys, and other similar lightweight metal applications. The purity of this grade of lithium metal enhances the finished product properties and is especially desirable within the aerospace and automotive industries.
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| Lithium Metal, Catalyst Grade
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| Market: Specialty Applications |
| SubMarket: Lithium Metal |
| CAS #: 7439-93-2 |
| Description: Lithium metal with a 1% max concentration of Sodium (Na),is used as a precursor in the synthesis of various pharmaceuticals and as a catalyst for polymerization.
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| Lithium Metal, High Purity Rod
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| Market: Specialty Applications |
| SubMarket: Lithium Metal |
| CAS #: 7439-93-2 |
| Description: The highest purity lithium metal available in a convenient 0.5 diameter x 6.5 length rod, packaged 1 lb per can, is a convenient size for use in laboratory and/or small scale operations.
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| Lithium Metal, Technical Grade
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| Market: Specialty Applications |
| SubMarket: Lithium Metal |
| CAS #: 7439-93-2 |
| Description: The unique properties of lithium metal allow it to be used in various applications. Lithium has an atomic number of 3 and an atomic weight of 6.941. It is slightly harder than sodium, but softer than lead, and is extremely light with a density of 0.531 g/cm3, or about half that of water. The wide range between the melting point of 180.5°C and the boiling point of 1336°C along with its excellent heat capacity makes lithium a good medium for heat sink or heat transfer applications. Lithium is also a strong reducing agent and reacts readily even with weak oxidizers--reacting with nitrogen at ambient temperature. Even though lithium is a powerful reducing agent in many reactions, it is less reactive than the other elements in the alkali metals group.
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| Lithium Methoxide (LiOMe) 10% in Methanol
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
| CAS #: 865-34-9 |
Description: LiOMe is a mild base used mainly in organic synthesis, most often in transesterifications. This reagent is offered currently in methanol solution of LiOMe (2.2M) and therefore is very easy to transfer from shipping container to storage or reactor. On contact with moisture, it is converted to methanol and lithium hydroxide causing the solution to become cloudy. For leading references, consult J. Mater. Res. 1999, 14, 1510.
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| Lithium Methoxide (LiOMe) 10% in Methanol
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| Market: Polymers |
| SubMarket: Polymer Additives |
| CAS #: 865-34-9 |
Description: LiOMe is a mild base used mainly in organic synthesis, most often in transesterifications. This reagent is offered currently in methanol solution of LiOMe (2.2M) and therefore is very easy to transfer from shipping container to storage or reactor.
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| Lithium Nitrate Anhydrous
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7790-69-4 |
| Description: Molten salt chemistry and metallurgy, antistatic agent for non-woven fabrics, oxidizing agent, flame colorant in flares and fireworks, etchant in glass manufacture.
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| Lithium Nitrate Solution
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 7790-69-4 |
| Description: Ammonia absorber in wastewater.
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| Lithium Orthophosphate, Tertiary
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 10377-52-3 |
| Description: Constituent in low-expansion porcelain enamel glazes and polymer intermediates.
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| Lithium Phosphate
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 10377-52-3 |
| Description: Constituent in low-expansion porcelain enamel glazes and polymer intermediates.
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| Lithium Sulfate Anhydrous
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 10377-48-7 |
| Description: In ceramic compositions as a source of lithia, as a solubilizer in photographic develop solutions, as a tracer in chemical products and as an additive to specialty Portland cements.
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| Lithium Sulfate Monohydrate
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 10102-25-7 |
| Description: Source of Lithia in ceramic compositions, solubilizer in photographic developer solutions, additive to Portland cements, and a tracer in chemical products.
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| Lithium t-Amoxide (LTA) in Heptane
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
| CAS #: 53535-81-2 |
Description: Lithium t-Amoxide is a strong base for organic synthesis. It can be used as an alternative to lithium tert-butoxide when ether solvents are to be avoided due to its greater solubility in hydrocarbons.
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| Lithium t-Butoxide (LTB) 2.0M in THF Solution
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
| CAS #: 1907-33-1 |
Description: LTB is a mild base used mainly in organic synthesis. It can also be used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity. This tetrahydrofuran (THF) solution of LTB is very easy to transfer from shipping container to storage or reactor. The solution is flammable and corrosive. Solutions tend to darken when exposed to air. On contact with moisture, LTB is converted to t-butanol and lithium hydroxide, causing the solution to become cloudy.
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| Lithium t-Butoxide (LTB) in 10% Heptane
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
| CAS #: 1907-33-1 |
Description: This heptane solution is a DEVELOPMENTAL formulation of lithium t-butoxide (LTB). LTB is a mild base used mainly in organic synthesis. It can also be used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity. For a brief review of this reagent, please consult Handbook of Reagents for Organic Synthesis, Acidic and Basic Reagents,1999 John Wiley & Sons, p. 208.
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| Lithium t-Butoxide Solid (LTB)
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| Market: Fine Chemicals |
| SubMarket: Lithium Alkoxides |
| CAS #: 1907-33-1 |
Description: LTB is a mild base used principally in organic synthesis. The pKa is 17. It can also be used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity. For a brief review of this reagent, please consult Handbook of Reagents for Organic Synthesis, Acidic and Basic Reagents,1999 John Wiley & Sons, p. 208.
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| Lithium Tetraborate Anhydrous
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| Market: Specialty Applications |
| SubMarket: Specialty Inorganics |
| CAS #: 12007-60-2 |
| Description: Flux in x-ray fluorescence analysis and as an additive to polycarbonate windows (especially in spacecraft) and lithium grease formulation.
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| Lithium tri-tert-butoxyaluminum hydride (TBLAH)
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| Market: Fine Chemicals |
| SubMarket: Metal Hydrides |
| CAS #: 17476-04-9 |
Description: Lithium tri-tert-butoxyaluminum hydride (TBLAH)is less reactive than lithium aluminum hydride (LAH) and is very useful in selective reductions of acyl halides, aldehydes, ketones, and esters. This reagent generally shows increased solubility, particularly at low temperatures in organic solvents. For reviews see: 1) H.C. Brown; J.Am.Chem.Soc. 1964, 86, 1089; 2) J. Malek; M. Cerny, Synthesis, 1972, 217; and 3) J. Malek, Org. React. 1985, 34,1.
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 LithMelt® Liquid - Anti / Deicer
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| Market: Construction |
| SubMarket: Anti-icer / Deicer |
| CAS #: 546-89-4, 127-08-2 |
| Description: LithMelt® anti-icing / deicing liquid is a specially formulated material comprising potassium acetate modified with lithium acetate to prevent the deleterious effects of standard potassium acetate on ASR.
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| Methyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 917-54-4 |
Description: MeLi is a formulation of methyllithium in THF/cumene that is non-pyrophoric and does not contain highly flammable diethyl ether. The product is stabilized through the addition of magnesium to yield a molar ratio of Li:Mg of 93:07. The presence of magnesium increases solubility and greatly reduces the rate of thermal decomposition, which can lead to the build-up of methane gas pressure. MeLi can be used for methylation via 1,2 addition to carbonyl or nitrile compounds. It is also useful in the preparation of vitamin and steroid derivatives, in carbene-type reactions in the formation of allenes and alkoxycyclopopanes, and in metalation reactions in the preparation of halogenated alkynyllithiums and steroidal alkynyl compounds. It can be used in the reduction of certain transition metal halides [e.g., PdCl2 to Pd (0)], in the preparation of lithium methyl cuprates for 1,4-conjugate addition, and to prepare other organometallics [e.g., Me2Mg, MeTi(NEt2)3, Me3Al, Me3As, Me3In or Me3Ga].
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| Methylmagnesium chloride in THF (MeMgCl)
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| Market: Fine Chemicals |
| SubMarket: Organomagnesiums |
| CAS #: 676-58-4 |
| Description: Methylmagnesium chloride, namely a Grignard reagent, is used primarily as an alkylating agent. This reagent readily adds a methyl group to carbonyl groups, such as aldehydes and ketones, providing synthetically useful routes to alcohols. Methylmagnesium chloride can also be used as a strong base in aprotic solvents. For reviews see: 1) J.Am.Chem.Soc. 1967, 89, 1964; 2) Synthesis 1977, 18; and 3) Pure Appl. Chem. 1980.
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| n-Butyllithium in branched octanes
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in branched octanes
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Cyclohexane (15% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL is a very strong base, exceedingly useful in organic synthesis. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Cyclohexane (15% soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Cyclohexane (20% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Cyclohexane (20% soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Cyclohexane (24% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Cyclohexane (24% soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Cyclohexane (Concentrate)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Cyclohexane (Concentrate)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Heptane (15% Soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Heptane (15% Soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Heptane (24% Soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Heptane (24% Soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Hexanes (15% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Hexanes (15% soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Hexanes (24% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Hexanes (24% Soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Hexanes (85% soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Hexanes (85% soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Toluene (10% Soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Toluene (10% Soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Butyllithium in Toluene (20% Soln)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 109-72-8 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. NBL has found particular utility in deprotonation and metal–halogen exchange reactions. NBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by NBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| n-Butyllithium in Toluene (20% Soln)
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 109-72-8 |
Description: As a polymer initiator, n-butyllithium is the most widely used initiator for anionic polymerization. Polymers such as styrenic thermoplastic elastomers(TPEs) and random SBR solution polymers for tires are produced using n-butyllithium.
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| n-Hexyllithium 33% in Hexanes (HxLi)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 21369-64-2 |
Description: n-Hexyllithium is a non-pyrophoric strong base, primarily used in organic synthesis in deprotonation reactions and as a lithiation reagent. The advantage of this reagent is that the by-product of a deprotonation reaction is n-hexanes. n-Hexanes is less volatile and has a higher flash point than the n-butane generated from a deprotonation with n-butyllithium. 1) The Chemistry of Organolithium Compounds; Pergamon: Oxford, 1974; 2) Organolithium Methods; Academic Press: London, 1988.
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| n-Octyllithium in Hexanes
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 3314-49-6 |
Description: Can be used as a non-pyrophoric substitute for n-butyllithium or when an octyl group is to be reacted with an electrophile.
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| n-Propyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
Description: This base is used as an alkylating or metalating reagent.
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| Phenyllithium 18.5% in DBE (PhLi)
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 591-51-5 |
Description: This patented (U. S. Patent 5,626,798) formulation of phenyllithium in dibutyl ether is non-pyrophoric and does not contain highly flammable diethyl ether. PhLi is particularly useful in lithium-halogen exchange reactions of aromatic heterocycles. PhLi can be used as a strong base, in organic synthesis, but generates benzene. It has been employed for the generation of ylides and benzynes. PhLi is more reactive than the phenyl Grignard reagent in nucleophilic additions to carbonyl and nitrile substrates. It is also useful in halide or alkoxide substitution/displacement reactions of inorganic compounds, such as phosphorus, silicon, tin and titanium. J. Organomet. Chem. 1988, 342, 143 and references therein.
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 Renew® Concrete Treatment
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| Market: Construction |
| SubMarket: Remediation |
| CAS #: 7790-69-4 |
| Description: Formulated lithium nitrate product designed to reduce expansion due to Alkali-Silica Reactivity (ASR) in hardened concrete. Used in remediation of pre-existing concrete structures and infrastructures presently affected by ASR.
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| sec-Butyllithium in Cyclohexane
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 598-30-1 |
Description: Used as a strong base in organic synthesis to improve yields and throughput in a reaction. SBL has found particular utility in the ortho metallation of aromatic substrates. SBL is also a very effective initiator of anionic polymerization of styrene and conjugated dienes. The synthesis of solution SBR and of styrenic thermoplastic elastomers (TPEs), in particular, is facilitated by SBL. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England.
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| sec-Butyllithium in Cyclohexane
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| Market: Polymers |
| SubMarket: Initiators |
| CAS #: 598-30-1 |
Description: As a polymer initiator, sec-butyllithium is used in anionic polymerization where faster initiation is required for specific grades of styrenic TPEs.
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| t-Butylphosphine (TBP)
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| Market: Fine Chemicals |
| SubMarket: Organophosphines |
| CAS #: 2501-94-2 |
Description: tert-Butylphosphine (TBP) is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions. For reviews see: 1) Palladium Reagents and Catalysts, John Wiley & Sons: Chichester, 1995 p. 345-356. 2) Advanced Synthesis & Catalysts, Wiley-VCH Verlag GmbH 2001 p. 118-136. 3) Tetrahedron: Asymmetry 204, 15 (17), 2621-2631 and references cited therein.
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| tert-Butyllithium (TBL) in Heptane
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 594-19-4 |
Description: This formulation of t-butyllithium (TBL) in heptane, while still pyrophoric has a significantly higher flash point than the traditional pentane formulation. TBL is particularly useful in lithium-halogen exchange reactions. TBL can be used as a strong base in organic synthesis. TBL is more reactive than the t-butyl Grignard reagent in nucleophilic additions to carbonyl and nitrile substrates. TBL is also useful in the displacement of halide or alkoxide ligands of inorganic compounds, such as Phosphorus, Silicon, Tin, and Titanium. References: The Chemistry of Organolithium Compounds, ed. Zvi Rappoport and Ilan Marek, Wiley, 2004, West Sussex, England
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| Tetrakis(ethylmethylamino)zirconium, TEMAZ
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| Market: Fine Chemicals |
| SubMarket: Transition Metal Amides |
| CAS #: 175923-04-3 |
Description: Tetrakis(ethylmethylamino)zirconium, TEMAZ, is a DEVELOPMENTAL product used as a precursor to make zirconium oxide films on silicon wafers for semiconductors. The high dielectric constant and relatively high thermal stability of zirconium oxide makes it attractive as a replacement for silicon dioxide.
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| Trimethylphosphine 30% in THF (TMP)
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| Market: Fine Chemicals |
| SubMarket: Organophosphines |
| CAS #: 594-09-2 |
Description: Trimethylphosphine is used in selective catalytic palladium coupling and ring opening reactions, as well as palladium-catalyzed hydrogenolysis reactions such as Suzuki, Stille, and Sonogashira. 1) J.Am.Chem.Soc. 1996, 118, 6329-6330; 2) Tett. Lett. 1999, 40 (51), 8955-8960; 3) Perkin / 2000, 22, 3808-3814 and references therein.
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| Trimethylsilylmethyllithium
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| Market: Fine Chemicals |
| SubMarket: Alkyllithiums and Aryllithiums |
| CAS #: 1822-00-0 |
Description: This base has an excellent utility in difficult heterocycle lithiation reactions.
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